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1 натронный способ варки целлюлозы
1) Oil: soda process2) Polymers: soda pulp-making processУниверсальный русско-английский словарь > натронный способ варки целлюлозы
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2 Mitscherlich, Alexander
SUBJECT AREA: Paper and printing[br]b. 28 May 1836 Berlin, Germanyd. 31 May 1918 Oberstdorf, Germany[br]German inventor of sulphite wood pulp for papermaking.[br]Mitscherlich had an impeccable scientific background; his father was the celebrated chemist Eilhardt Mitscherlich, discoverer of the law of isomorphism, and his godfather was Alexander von Humboldt. At first his progress at school failed to live up to this auspicious beginning and his father would only sanction higher studies if he first qualified as a teacher so as to assure a means of livelihood. Alexander rose to the occasion and went on to gain his doctorate at the age of 25 in the field of mineralogical chemistry. He worked for a few years as Assistant to the distinguished chemists Wöhler in Göttingen and Wurtz in Paris. On his father's death in 1863, he succeeded him as teacher of chemistry in the University of Berlin. In 1868 he accepted a post in the newly established Forest Academy in Hannoversch-Munden, teaching chemistry, physics and geology. The post offered little financial advantage, but it left him more time for research. It was there that he invented the process for producing sulphite wood pulp.The paper industry was seeking new raw materials. Since the 1840s pulp had been produced mechanically from wood, but it was unsuitable for making fine papers. From the mid-1860s several chemists began tackling the problem of separating the cellulose fibres from the other constituents of wood by chemical means. The American Benjamin C.Tilghman was granted patents in several countries for the treatment of wood with acid or bisulphite. Carl Daniel Ekman in Sweden and Karl Kellner in Austria also made sulphite pulp, but the credit for devising the process that came into general use belongs to Mitscherlich. His brother Oskar came to him at the Academy with plans for producing pulp by the action of soda, but the results were inferior, so Mitscherlich substituted calcium bisulphite and in the laboratory obtained good results. To extend this to a large-scale process, he was forced to set up his own mill, where he devised the characteristic towers for making the calcium bisulphite, in which water trickling down through packed lime met a rising current of sulphur dioxide. He was granted a patent in Luxembourg in 1874 and a German one four years later. The sulphite process did not make him rich, for there was considerable opposition to it; government objected to the smell of sulphur dioxide, forestry authorities were anxious about the inroads that might be made into the forests and his patents were contested. In 1883, with the support of an inheritance from his mother, Mitscherlich resigned his post at the Academy to devote more time to promoting his invention. In 1897 he at last succeeded in settling the patent disputes and achieving recognition as the inventor of sulphite pulp. Without this raw material, the paper industry could never have satisfied the insatiable appetite of the newspaper presses.[br]Further ReadingH.Voorn "Alexander Mitscherlich, inventor of sulphite wood pulp", Paper Maker 23(1): 41–4.LRDBiographical history of technology > Mitscherlich, Alexander
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3 Viscose
Viscose was discovered by two English chemists, Charles F. Cross and E. J. Be van, working in collaboration at Kew, near London, who found that when cellulose was treated with disulphide of carbon in the presence of caustic soda, it was converted into a golden yellow plastic compound which dissolved readily in water. A solution of the plastic was of such viscosity that it was named " viscose," a name that was destined to become world famous, seeing that round about 88 per cent of the world production of rayon is now made by the viscose process. In 1892 Cross and Bevan were granted a patent on the viscose process and it was applied to many purposes before the production of a textile thread was successfully accomplished. Fundamentally, the manufacture of viscose rayon is fairly simple. The raw material may be wood pulp, pulp from cotton linters, or a mixture of the two. The greater part of the world's viscose is made from wood pulp. Viscose rayon manufacture comprises seven distinct treatments as follows: - 1. Making and purifying the cotton or wood pulp which forms the cellulose base. 2. Caustic soda treatment of the cellulose base thereby forming alkali cellulose. 3. Treatment of alkali cellulose with carbon disulphide, forming cellulose xanthate. 4. Dissolving the cellulose xanthate in weak caustic soda to form cellulose solution or viscose. 5. Spinning viscose into yarn. 6. Bleaching, purification and finishing of the yarn. 7. Preparing the yarn for weaving and knitting. -
4 Bevan, Edward John
[br]b. 11 December 1856 Birkenhead, Englandd. 17 October 1921 London, England[br]English co-inventor of the " viscose rayon " process for making artificial silk.[br]Bevan began his working life as a chemist in a soap works at Runcorn, but later studied chemistry at Owens College, Manchester. It was there that he met and formed a friendship with C.F. Cross, with whom he started to work on cellulose. Bevan moved to a paper mill in Scotland but then went south to London, where he and Cross set up a partnership in 1885 as consulting and analytical chemists. Their work was mainly concerned with the industrial utilization of cellulose, and with the problems of the paper and jute industries. Their joint publication, A Text-book of Paper-making, which first appeared in 1888 and went into several editions, became the standard reference and textbook on the subject. The book has a long introductory chapter on cellulose.In 1892 Cross, Bevan and Clayton Beadle discovered viscose, or sodium cellulose xanthate, and took out the patent which was to be the foundation of the "viscose rayon" industry. They had their own laboratory at Station Avenue, Kew Gardens, where they carried out much work that eventually resulted in viscose: cellulose, usually in the form of wood pulp, was treated first with caustic soda and then with carbon disulphide to form the xanthate, which was then dissolved in a solution of dilute caustic soda to produce a viscous liquid. After being aged, the viscose was extruded through fine holes in a spinneret and coagulated in a dilute acid to regenerate the cellulose as spinnable fibres. At first there was no suggestion of spinning it into fibre, but the hope was to use it for filaments in incandescent electric light bulbs. The sheen on the fibres suggested their possible use in textiles and the term "artificial silk" was later introduced. Cross and Bevan also discovered the acetate "Celanese", which was cellulose triacetate dissolved in acetone and spun in air, but both inventions needed much development before they could be produced commercially.In 1892 Bevan turned from cellulose to food and drugs and left the partnership to become Public Analyst to Middlesex County Council, a post he held until his death, although in 1895 he and Cross published their important work Cellulose. He was prominent in the affairs of the Society of Public Analysts and became one of its officials.[br]Bibliography1888, with C.F.Cross, A Text-book of Papermaking.1892, with C.F.Cross and C.Beadle, British patent no. 8,700 (viscose). 1895, with C.F.Cross, Cellulose.Further ReadingObituary, 1921, Journal of the Chemical Society.Obituary, 1921, Journal of the Society of Chemical Industry.Edwin J.Beer, 1962–3, "The birth of viscose rayon", Transactions of the Newcomen Society 35 (an account of the problems of developing viscose rayon; Beer worked under Cross in the Kew laboratories).RLH
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